问题：Hudlicky's Reductions in Organic Chemistry 有机化学中的还原反应-322页，1984年
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提问：Yan
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版块：有机化学资源(yjgzfl,netpanda,)
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时间：2005-02-22 21:06:49 编辑加入/取消收藏订制/取消短消息举报该贴

ftp://down@chemforum.vicp.net/in/ReductionsinOrganicChemistr.pdf

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[该帖子已被Yan在2005-2-22 21:08:00编辑过]

回复人：Yan,★ (他山之石，可以攻玉) 时间：2005-02-22 21:20:06 编辑

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3.95M
相对于取代反应，还原反应和氧化反应是两类比较复杂的反应。

Angewa上的book review对该书的介绍
Reductions in Organic Chemistry. By M. Hudlicky. Ellis
Horwood Ltd., Chichester 1984. xvi, 309 pp., hardback,

This book claims to present a comprehensive coverage
of all types of reduction reactions. The author attempts to
link the numerous classes of compounds and the various
different methods of reduction in a sort of matrix in order
to reach his difficult goal. With the choice of predominantly
very simple model compounds, the neglect of stereochemical
problems and the uncritical juxtaposition of
important and unimportant methods, the author pays a
high price to achieve his aim.
The introductory chapter covers catalytic hydrogenations,
reductions with hydrides and hydrido-complexes,
E 35.00.--ISBN 0-85312-345-4
electroreductions, and reductions with metals and non-metallic
reagents.
For the sake of clarity, it would have been better to dispense
with experimental details and large-scale diagrams
of apparatus at this point, especially since these are presented
again, at some length, in an experimental appendix.
The reductions of nearly all classes of compounds are
listed in the main part of the book, accompanied by an
abundance of examples. In this way completeness is
achieved, but a discussion of problems of regio- and stereoselectivity
and their basis in reaction mechanisms,
which would have been appropriate, is lost. The field of
reductions with chiral reagents, which has been the focus
of much recent attention, is indeed broached here and there in the book but surely deserves a more detailed treatment.
Preparative chemists will find useful the tables that follow
the main chapter, in which are grouped important
types of educt, reduction reagents and products. These
tables refer back into the main body of the text and thence
to an extensive literature index.
The last part of the book consists of fifty experimental
procedures for the preparation of special reduction reagents
and for the reduction of representative compounds.
Since the compounds chosen have got quite simple structures,
these procedures can serve only as a guide; for more
complicated molecules it would certainly be advisable to
consult the original literature.
This book does not, then, offer a critical view, but
simply a superficial description of the extensive arsenal of
reduction methods. For the practical chemist there is use-
Tul guidance, especially in the numerous tables and experimental
procedures. The very high price is bound to stand
in the way of purchase for everyday use.
Franz-Peter Montforts [NB 712 IE]
Institut fur Organische Chemie
der Universitat Frankfurt (FRG)

回复人：Yan,★ (他山之石，可以攻玉) 时间：2005-02-22 21:23:05 编辑

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第二版目录，与第一版主要内容相差不大

http://www.oup.com/us/catalog/general/subject/Chemistry/OrganicChemistry/?view=usa&ci=0841233446

Table of Contents
Preface to the First Edition
Preface to the Second Edition
Introduction
Safety First
Abbreviations and Proprietary Names
Categories of Reductions:
Catalytic Hydrogenation
Reduction with Hydrides and Complex Hydrides
Electroreduction and Reductions with Metals
Reductions with Metal Compounds
Reductions with Nonmetal Compounds
Reduction of Specific Types of Organic Compounds
Reduction of Hydrocarbons and Aromatic Heterocycles
Reduction of Halogen Derivatives of Hydrocarbons and Basic Heterocycles
Reduction of Nitro, Nitroso, Diazo, and Azido Derivatives of Hydrocarbons and Basic Heterocycles
Reduction of Sulfur Compounds (Except Sulfur Derivatives of Aldehydes, Ketones, and Acids)
Reduction of Amines and Their Derivatives and of Phosphorus Compounds
Reduction of Aldehydes and Their Derivatives
Reduction of Ketones and Their Derivatives
Reduction of Carboxylic Acids
Reduction of Acyl Chlorides and Acid Anhydrides
Reduction of Nitriles
Reduction of Organometallic Compounds
Correlation Tables
Reduction of Alkanes, Alkenes, Alkadienes, and Alkynes
Reduction of Aromatic Hydrocarbons
Reduction of Heterocyclic Aromatic Compounds
Reduction of Halogen Compounds
Reduction of Nitro Compounds
Reduction of Nitroso, Diazonium and Azido Compounds
Reduction of Alcohols and Phenols
Reduction of Ethers
Reduction of Epoxides, Peroxides, and Ozonides
Reduction of Sulfur Compounds (Except Sulfur Derivatives of Aldehydes, Ketones, and Acids)
Reduction of Amines and Their Derivatives
Reduction of Phosphorus Compounds
Reduction of Aldehydes
Reduction of Derivatives of Aldehydes
Reduction of Ketones
Reduction of Substitution Derivatives of Ketones
Reduction of Hydroxy Ketones, Diketones, and Quinones
Reduction of Ketals, Thioketals, Ketimines, Ketoximes, and Hydrazones
Reduction of Carboxylic Acids
Reduction of Derivatives of Carboxylic Acids
Reduction of Acyl Chlorides and Acid Anhydrides
Reduction of Esters of Carboxylic Acids
Reduction of Esters of Unsaturated Carboxylic Acids
Reduction of Substitution Derivatives of Esters
Reduction of Functionalized Esters
Reduction of Amides, Lactams, and Imides
Reduction of Amidines, Thioamides, Imidoyl Chlorides and Hydrazides
Reduction of Nitriles
Catalytic Hydrogenation with Hydrogen Generated from Sodium Borohydride
Catalytic Hydrogenation Under Elevated Pressure
Preparation of Palladium Catalyst
Preparation of the Lindlar Catalyst
Reduction with Raney Nickel
Desulfurization with Raney Nickel
Preparation of Nickel Catalyst
Catalytic Transfer of Hydrogen
Homogeneous Hydrogenation
Preparation of Alane (Aluminum Hydride)
Preparation of Lithium Tris(tert-butoxy)aluminum Hydride
Analysis of Hydrides and Complex Hydrides
Reduction with Lithium Triethoxylaluminum Hydride
Reduction with Lithium Tris-tert-butoxyaluminum Hydride
Reduction with Lithium Aluminum Hydride and Diethylamine
Reduction with Lithium (1,1'-Binaphthyl-2,2'-dioxy)ethoxyaluminum Hydride
Reduction with Alane (Aluminum Hydride) In Situ
Reduction with Diisobutylalane
Reduction with Borane
Reduction with Borane In Situ
Reduction with Thexylchloroborane-Dimethyl Sulfide
Reduction with Sodium Borohydride
Reduction with Zinc Borohydride
Reduction with Sodium Cyanoborohydride
Reduction with Triethylsilane
Reduction with Zinc Borohydride
Reduction with Triethylsilane
Reduction with Stannanes
Electrolytic Reduction
Reduction with Sodium(Birch Reduction) Reduction with Sodium
Reduction with Sodium Naphthalene
Reduction with Sodium Amalgam
Reduction with Nickel-Aluminum Alloy
Reduction with Zinc (Clemmensen Reduction)
Reduction with Zinc in Alkaline Solution
Reduction with Zinc and Sodium Iodide
Reduction with Iron
Reduction with Tin
Reduction with Stannous Chloride
Reduction with Chromous Chloride
Reduction with Vanadous Chloride
Reduction with Hydriodic Acid
Reduction with Sulfur Dioxide
Reduction with Sodium Sulfite
Reduction with Sodium Hydrosulfite (Dithionite)
Reduction with Sodium dithionite in the Presence of a Phase-Transfer Catalyst
Reduction with Hydrazine
Reduction with Hypophosphorous Acid
Reduction with Ammonium Hypophosphite
Reduction with Trialkyl Phosphites
Reduction with Methyltrichlorosilane and Sodium Iodie
Reduction with Alcohols
Reductive Amination (Leuckart Reaction)
Reductions with 1,4-dihydropyridine Derivatives
Biochemical Reduction
Enantioselective Reduction with Baker's Yeast
Microbial Reductions

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回复人：就想歇会儿,▲ () 时间：2005-04-07 15:44:48 编辑	3楼
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