问题：哪位大侠帮忙查询msds 谢谢!
类型：求助 (悬赏分:3分)
提问：cjy
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版块：有机化学问题(jimuwei,fpcwin1211,netpanda,yjgzfl,Ftian,)
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时间：2006-01-12 10:35:59 编辑加入/取消收藏订制/取消短消息举报该贴

中文版间苯二甲醛的MSDS?谢谢!还有乙烯基溴化镁MSDS。谢谢!

回复人：qyl1970,★ (专注于有机合成，接受公斤级化合物定制。) 时间：2006-01-12 12:12:16 编辑

1楼

找英文版的自己翻译吧.中文版的恐怕没有吧!
间苯二甲醛有英文版如下:
SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 01/11/2006
Date Updated: 04/03/2004
Version 1.2
Section 1 - Product and Company Information
Product Name ISOPHTHALALDEHYDE
Product Number 59195
Brand FLUKA
Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS MO 63103 US
Technical Phone: 314 771 5765
Emergency Phone: 414 273 3850 Ext. 5996
Fax: 800 325 5052
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
ISOPHTHALALDEHYDE 626-19-7 No
Formula C8H6O2
Synonyms Isophtaldehydes (French)
RTECS Number: NT1981000
Section 3 - Hazards Identification
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.
EYE EXPOSURE
In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.
Section 5 - Fire Fighting Measures
FLASH POINT
N/A
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and
heavy rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Avoid inhalation. Avoid contact with eyes, skin,
and clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep tightly closed. Store in a cool dry place.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN
(EU). Respiratory protection is not required. Where protection
from nuisance levels of dusts are desired, use type N95 (US) or
type P1 (EN 143) dust masks.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
Section 9 - Physical/Chemical Properties
Appearance Color: Light yellow
Form: Powder
Property Value At Temperature or Pressure
Molecular Weight 134.13 AMU
pH N/A
BP/BP Range N/A
MP/MP Range 87 °C
FLUKA - 59195 www.sigma-aldrich.com Page 2
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Materials to Avoid: Strong oxidizing agents, Strong bases.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Eye Contact: May cause eye irritation.
Multiple Routes: May be harmful by inhalation, ingestion, or
skin absorption.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
TOXICITY DATA
Intravenous
Mouse
100 MG/KG
LD50
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Dissolve or mix the material with a combustible solvent and burn
FLUKA - 59195 www.sigma-aldrich.com Page 3
in a chemical incinerator equipped with an afterburner and
scrubber. Observe all federal, state, and local environmental
regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: None
Non-Hazardous for Transport: This substance is
considered to be non-hazardous for transport.
IATA
Non-Hazardous for Air Transport: Non-hazardous for air
transport.
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
S: 22-24/25
Safety Statements: Do not breathe dust. Avoid contact with skin
and eyes.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: No
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2006 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
FLUKA - 59195 www.sigma-aldrich.com Page 4

回复人：qyl1970,★ (专注于有机合成，接受公斤级化合物定制。) 时间：2006-01-12 12:15:26 编辑

2楼

SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 01/11/2006
Date Updated: 04/05/2004
Version 1.4
Section 1 - Product and Company Information
Product Name VINYLMAGNESIUM BROMIDE, 1.0M
SOLUTION IN TETRAHYDROFURAN
Product Number 225584
Brand ALDRICH
Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS MO 63103 US
Technical Phone: 314 771 5765
Emergency Phone: 414 273 3850 Ext. 5996
Fax: 800 325 5052
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
VINYLMAGNESIUM BROMIDE, 1.0M None No
SOLUTION IN TETRAHYDROFURAN
Ingredient Name CAS # Percent SARA 313
VINYLMAGNESIUM BROMIDE 1826-67-1 13.395 No
TETRAHYDROFURAN (Inhibitor free) 109-99-9 86.605 No
Formula C2H3BrMg
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Flammable (USA) Highly Flammable (EU). Corrosive.
Reacts violently with water. May form explosive peroxides. Causes
burns. Limited evidence of a carcinogenic effect.
Possible Carcinogen (US). Target organ(s): Central nervous system.
Liver.
HMIS RATING
HEALTH: 3*
FLAMMABILITY: 3
REACTIVITY: 2
SPECIAL HAZARD(S): Water reactive
NFPA RATING
HEALTH: 3
FLAMMABILITY: 3
REACTIVITY: 2
SPECIAL HAZARD(S): Water reactive
*additional chronic hazards present.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician. Do not induce vomiting.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLAMMABLE HAZARDS
Flammable Hazards: Yes
Peroxide Former: Yes
EXPLOSION HAZARDS
Vapor may travel considerable distance to source of ignition and
flash back. Container explosion may occur under fire conditions.
CONDITIONS OF FLAMMABILITY
Reacts with water to liberate flammable and/or explosive gas.
FLASH POINT
1.4 °F - 17.0 °C Method: closed cup
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Dry chemical powder.
Unsuitable: Do not use water.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Flammable liquid. Vapor may travel
considerable distance to source of ignition and flash back.
Emits toxic fumes under fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition. Use nonsparking
tools.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and
heavy rubber gloves.
METHODS FOR CLEANING UP
Cover with dry-lime, sand, or soda ash. Place in covered
ALDRICH - 225584 www.sigma-aldrich.com Page 2
containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is
complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Do not breathe vapor. Do not get in eyes, on
skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Store under inert gas. Keep container closed. Keep
away from heat, sparks, and open flame. Store in a cool dry
place.
Unsuitable: In the absence of inhibitors, tetrahydrofuran tends
to absorb and react with oxygen from the air to form explosive
peroxides which may detonate when they become concentrated by
evaporation or distillation, are combined with other compounds
resulting in an explosive mixture or are disturbed by heat,
shock, or friction.
Incompatible Materials: Do not allow contact with water
SPECIAL REQUIREMENTS
Handle and store under inert gas. Do not distill to dryness.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Use nonsparking tools. Use only in a
chemical fume hood.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN
(EU). Where risk assessment shows air-purifying respirators are
appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as
a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
Other: Faceshield (8-inch minimum).
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Discard contaminated shoes. Remove
and wash contaminated clothing promptly.
Section 9 - Physical/Chemical Properties
Appearance Physical State: Clear liquid
Color: Orange-Brown
Property Value At Temperature or Pressure
Molecular Weight 131.27 AMU
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
ALDRICH - 225584 www.sigma-aldrich.com Page 3
SG/Density 0.98 g/cm3
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point 1.4 °F - 17.0 °C Method: closed cup
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Conditions of Instability: May decompose on exposure to light.
Conditions to Avoid: Do not allow water to enter container because
of violent reaction.
Materials to Avoid: Water, Oxygen, Oxidizing agents, Alcohols,
Acids.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Magnesium oxide, Hydrogen bromide gas.
Hazardous Decomposition Products Formed Upon Contact with Water:
Reacts with water to liberate flammable and/or explosive gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes burns.
Inhalation: May be harmful if inhaled. Material is extremely
destructive to the tissue of the mucous membranes and upper
respiratory tract.
Ingestion: May be harmful if swallowed.
TARGET ORGAN(S) OR SYSTEM(S)
Kidneys. Liver. Central nervous system.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Material is extremely destructive to tissue of the mucous
membranes and upper respiratory tract, eyes, and skin.
Inhalation may result in spasm, inflammation and edema of the
larynxand bronchi, chemical pneumonitis, and pulmonary edema.
ALDRICH - 225584 www.sigma-aldrich.com Page 4
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting. Can cause CNS depression. Exposure to high airborne
concentrations can cause anesthetic effects.
CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that has been
reported to be possibly carcinogenic based on its IARC, ACGIH,
NTP, or EPA classification.
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Burn in a chemical incinerator equipped with an
afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Observe all federal, state, and
local environmental regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: Organometallic substance,
liquid, water-reactive, flammable
UN#: 3399
Class: 4.3
Packing Group: Packing Group II
Hazard Label: Dangerous when wet
Hazard Label: Flammable liquid
PIH: Not PIH
IATA
Proper Shipping Name: Organometallic substance,
liquid, water-reactive, flammable
IATA UN Number: 3399
Hazard Class: 4.3
Packing Group: II
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: F-C
Indication of Danger: Highly Flammable. Corrosive.
R: 11-14-19-34
Risk Statements: Highly flammable. Reacts violently with water.
May form explosive peroxides. Causes burns.
S: 16-29-33-26-36/37/39-45
Safety Statements: Keep away from sources of ignition - no
smoking. Do not empty into drains. Take precautionary measures
against static discharges. In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable protective clothing, gloves, and eye/face protection.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Flammable (USA) Highly Flammable (EU).
Corrosive.
ALDRICH - 225584 www.sigma-aldrich.com Page 5
Risk Statements: Reacts violently with water. May form explosive
peroxides. Causes burns. Limited evidence of a carcinogenic
effect.
Safety Statements: Keep away from sources of ignition - no
smoking. Do not empty into drains. Take precautionary measures
against static discharges. In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable protective clothing, gloves, and eye/face protection.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
US Statements: Possible Carcinogen (US). Target organ(s):
Central nervous system. Liver.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: No
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2006 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
ALDRICH - 225584 www.sigma-aldrich.com Page 6

回复人：flyczw,▲ (我的QQ113492333欢迎联系-合成六员氮杂环结构-吡啶-哌啶-氮杂吲哚-吡啶并三氮唑-嘧啶) 时间：2006-01-12 20:47:00 编辑	3楼
象这类问题可以自己解决先用化工字典：http://www.cnreagent.com/tools/namedb/ 查英文名和CAS# 然后进入http://www.chemexper.com/查找一般的都能查到查不到的再到论坛上问高手

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