定制各类格氏试剂

问题:求10氯-3-甲氧基丙烷的工艺
类型:求助 (悬赏分:3分)
提问:marcol2000
等级:
版块:有机化学问题(jimuwei,fpcwin1211,netpanda,yjgzfl,Ftian,)
信誉:57%
回复:6
阅读:1256
时间:2006-03-02 15:32:42  编辑    加入/取消收藏    订制/取消短消息    举报该贴    

我想在实验室做1-氯-3-甲氧基丙烷,不知道去哪查它的合成条件。
现在工业生产都是什么方法。
谢谢
cas:36215-07-3
查合成路线有什么好的网站没有?
回复人:nakata,▲▲▲▲▲ () 时间:2006-03-02 17:39:15   编辑 1楼
1-Chloro-3-methoxypropane


回复人:nakata,▲▲▲▲▲ () 时间:2006-03-02 17:43:16   编辑 2楼
METHOD OF 1-PHENYL-1-CHLORO-3-METHOXYPROPANE SYNTHESIS
http://v3.espacenet.com/origdoc?DB=EPODOC&IDX=SU1735263&F=0&QPN=SU1735263
相似的,不过没用,你也看不懂



回复人:ecustlian,▲▲▲ (相互学习,共同提高) 时间:2006-03-02 20:03:52   编辑 3楼
Reaction ID 6947323
Product BRN 1731202 1-chloro-3-methoxy-propane
No. of Reaction Details 1
Find similar reactions not available

Field Availability List (Beilstein(2005/03):Reactions:Q02 hit 11, RX.ID 6947323)
Code Field Name Occ.
RX Reaction Details 1

Reaction Details (Beilstein(2005/03):Reactions:Q02 hit 11, RX.ID 6947323)
Reaction Classification Preparation (half reaction)
Ref. 1 3178422; Journal; Kharasch et al.; JACSAT; J. Am. Chem. Soc.; 83; 1961; 3233.
Ref. 2 5211202; Journal; Taeger; Bergk; JPCEAO; J. Prakt. Chem.; 35; 1967; 1.

RX.ID=6947323:




回复人:ecustlian,▲▲▲ (相互学习,共同提高) 时间:2006-03-02 20:04:09   编辑 4楼
Reaction ID 9262408
Reactant BRN 605278 1-bromo-3-chloro-propane

1098229 methanol
Product BRN 1731202 1-chloro-3-methoxy-propane
No. of Reaction Details 1
Find similar reactions click here

Field Availability List (Beilstein(2005/03):Reactions:Q02 hit 12, RX.ID 9262408)
Code Field Name Occ.
RX Reaction Details 1

Reaction Details (Beilstein(2005/03):Reactions:Q02 hit 12, RX.ID 9262408)
Reaction Classification Preparation
Yield 47 percent (BRN=1731202)
Reagent CH3ONa
Temperature 20 C
Ref. 1 6379682; Journal; Lebl, Tomas; Smicka, Ales; Brus, Jiri; Bruhn, Clemens; EJICFO; Eur. J. Inorg. Chem.; EN; 1; 2003; 143 - 148.

RX.ID=9262408:




回复人:ecustlian,▲▲▲ (相互学习,共同提高) 时间:2006-03-02 20:04:33   编辑 5楼
Reaction ID 5804007
Reactant BRN 1730731 ethene
Reactant BiCl3
Reactant BRN 505943 chloro-methoxy-methane
Product BRN 1731202 1-chloro-3-methoxy-propane
No. of Reaction Details 2
Find similar reactions click here

Field Availability List (Beilstein(2005/03):Reactions:Q02 hit 10, RX.ID 5804007)
Code Field Name Occ.
RX Reaction Details 2

Reaction Details 1 of 2 (Beilstein(2005/03):Reactions:Q02 hit 10, RX.ID 5804007)
Reaction Classification Chemical behaviour
Temperature 80 C
Other Conditions unter Druck
Note 1 Handbook
Ref. 1 1343464; Patent; du Pont de Nemours & Co.; US 2024749; 1932.

Reaction Details 2 of 2 (Beilstein(2005/03):Reactions:Q02 hit 10, RX.ID 5804007)
Reaction Classification Chemical behaviour
Temperature 80 C
Pressure 36039.9 - 41188.4 Torr

RX.ID=5804007:




回复人:ecustlian,▲▲▲ (相互学习,共同提高) 时间:2006-03-02 20:05:29   编辑 6楼
Reaction ID 3308813
Reactant BRN 605278 1-bromo-3-chloro-propane
Product BRN 1731202 1-chloro-3-methoxy-propane
No. of Reaction Details 1
Find similar reactions click here

Field Availability List (Beilstein(2005/03):Reactions:Q02 hit 8, RX.ID 3308813)
Code Field Name Occ.
RX Reaction Details 1

Reaction Details (Beilstein(2005/03):Reactions:Q02 hit 8, RX.ID 3308813)
Reaction Classification Preparation
Ref. 1 5585799; Journal; Shinoda, Kiyonori; Yasuda, Kensei; JOCEAH; J. Org. Chem.; EN; 56; 12; 1991; 4081-4084.

RX.ID=3308813:


--------------------------------------------------------------------------------
Beilstein Data: Copyright (c) 1988-2005, Beilstein Institut zur Foerderung der Chemischen Wissenschaften licensed to Beilstein GmbH and MDL Information Systems GmbH. All rights reserved.
Reaction (Beilstein(2005/03):Reactions:Q02 hit 8, RX.ID 3308813)
Reaction ID 3308813
Reactant BRN 605278 1-bromo-3-chloro-propane
Product BRN 1731202 1-chloro-3-methoxy-propane
No. of Reaction Details 1
Find similar reactions click here

Field Availability List (Beilstein(2005/03):Reactions:Q02 hit 8, RX.ID 3308813)
Code Field Name Occ.
RX Reaction Details 1

Reaction Details (Beilstein(2005/03):Reactions:Q02 hit 8, RX.ID 3308813)
Reaction Classification Preparation
Ref. 1 5585799; Journal; Shinoda, Kiyonori; Yasuda, Kensei; JOCEAH; J. Org. Chem.; EN; 56; 12; 1991; 4081-4084.

RX.ID=3308813:






问题讨论没有结束...
您尚未进入本论坛,登录之后才可以回贴
用户名:密码:    游客  新用户免费注册
7msec



版权所有 中国化学化工论坛 
可转载本站文章 但请务必注明出处 本站法律顾问 方利律师  
www.ccebbs.com E-Mail:ccebbs00@126.com
Chinese Chemistry and Chemical Engineering BBS