问题：1-环已烯基乙腈怎么合成
类型：求助 (悬赏分:3分)
提问：petroboy
等级：▲
版块：药物化学(jaywoo,合成小象,)
信誉：56%
回复：3
阅读：773
时间：2006-03-14 10:25:24 编辑加入/取消收藏订制/取消短消息举报该贴

1-环已烯基乙腈是怎么合成的,请指教.

[该帖子已被petroboy在2006-3-14 10:28:49编辑过]

回复人：ecustlian,▲▲▲ (相互学习,共同提高) 时间：2006-03-14 19:07:45 编辑

1楼

Ref. 1 3969816; Journal; Balasubrahmanyam; Balasubramanian; TETRAB; Tetrahedron; 29; 1973; 683,688.
Ref. 2 4109575; Patent; Knapsack-Griesheim; DE 1108685; 1958; Chem.Abstr.; EN; 57; 3320.
Ref. 3 4242494; Journal; Messina et al.; CINMAB; Chim.Ind.(Milan); 61; 1979; 106.
Ref. 4 3590105; Journal; House et al.; JOCEAH; J. Org. Chem.; 40; 1975; 1460,1461,1466.
Ref. 5 4352254; Journal; Oritani et al.; ABCHA6; Agric. Biol. Chem.; 37; 1973; 261,262, 266.
Ref. 6 3242017; Journal; Moriconi; Mazzocchi; JOCEAH; J. Org. Chem.; 31; 1966; 1372,1377.
Ref. 7 3233703; Journal; McKay et al.; JOCEAH; J. Org. Chem.; 26; 1961; 76.
Ref. 8 4881723; Journal; Achrem et al.; BACCAT; Bull.Acad.Sci.USSR Div.Chem.Sci.(Engl.Transl.); 1962; 984; IASKA6; Izv. Akad. Nauk SSSR Ser. Khim.; 1962; 1050.
Ref. 9 2939921; Journal; House et al.; JACSAT; J. Am. Chem. Soc.; 82; 1960; 1457,1460.

回复人：ecustlian,▲▲▲ (相互学习,共同提高) 时间：2006-03-14 19:08:37 编辑

2楼

Reaction ID 5589425
Reactant 1-acetoxy-cyclohexane-carbinitrile-(1)
Product BRN 385837 cyclohex-1-enecarbonitrile
No. of Reaction Details 1
Find similar reactions not available

Field Availability List (Beilstein(2005/03):Reactions:Q01 hit 22, RX.ID 5589425)
Code Field Name Occ.
RX Reaction Details 1

Reaction Details (Beilstein(2005/03):Reactions:Q01 hit 22, RX.ID 5589425)
Reaction Classification Preparation (half reaction)
Temperature 440 - 450 C
Other Conditions Leiten im Stickstoff-Strom ueber Quarz
Note 1 Handbook
Ref. 1 1549407; Journal; Burns; Jones; Ritchie; JCSOA9; J. Chem. Soc.; 1935; 400, 405.

RX.ID=5589425:

回复人：ecustlian,▲▲▲ (相互学习,共同提高) 时间：2006-03-14 19:09:39 编辑

3楼

Reaction ID 5589426
Reactant 2-chloro-cyclohexane-carbonitrile-(1)
Product BRN 385837 cyclohex-1-enecarbonitrile
No. of Reaction Details 2
Find similar reactions not available

Field Availability List (Beilstein(2005/03):Reactions:Q01 hit 23, RX.ID 5589426)
Code Field Name Occ.
RX Reaction Details 2

Reaction Details 1 of 2 (Beilstein(2005/03):Reactions:Q01 hit 23, RX.ID 5589426)
Reaction Classification Preparation (half reaction)
Reagent aq. NaOH solution
Note 1 Handbook
Ref. 1 1830407; Journal; Cocker; Lapworth; Peters; JCSOA9; J. Chem. Soc.; 1931; 1382, 1390.
Ref. 2 2094151; Journal; van Coillie; BSCBAG; Bull. Soc. Chim. Belg.; 42; 1933; 419, 423.

Reaction Details 2 of 2 (Beilstein(2005/03):Reactions:Q01 hit 23, RX.ID 5589426)
Reaction Classification Preparation (half reaction)
Reagent pyridine
Note 1 Handbook
Ref. 1 1830407; Journal; Cocker; Lapworth; Peters; JCSOA9; J. Chem. Soc.; 1931; 1382, 1390.
Ref. 2 2094151; Journal; van Coillie; BSCBAG; Bull. Soc. Chim. Belg.; 42; 1933; 419, 423.

RX.ID=5589426:

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