问题：谁知道SmI2的制备方法？
类型：求助 (悬赏分:3分)
提问：rrrzzz
等级：▲
版块：元素及金属有机(方无忧,seaword,)
信誉：77%
回复：4
阅读：1292
时间：2006-03-17 07:57:01 编辑加入/取消收藏订制/取消短消息举报该贴

请告知！谢了

回复人：tangyyer,★★★★★ (有空来逛逛my blog: http://tangyyer.blog.hexun.com) 时间：2006-03-17 08:07:55 编辑

1楼

To a mixture of samarium powder (5.32 mmol) and 1,2-diiodoethane (4.0 mmol) was added THF (10 mL) at room temperature and under argon. A mild exothermic reaction proceeded rapidly. The reaction mixture was stirred at room temperature for 10 minutes and then more THF (20 mL) was added. After the reaction mixture was stirred for 1 h, an intense blue-green solution of SmI2 was obtained. A solution of the substrate in THF/MeOH (2:1) was added to the above solution.
可以参见：Girard, P.; Namy, J.L.; Kagan, H.B. J. Am. Chem. Soc. 1980, 102, 2693.

回复人：chemsolve,▲▲ (expert in OLED and PLED) 时间：2006-03-17 08:08:46 编辑	2楼
http://www.iupac.org/publications/pac/1988/pdf/6011x1725.pdf

回复人：chemsolve,▲▲ (expert in OLED and PLED) 时间：2006-03-17 08:09:52 编辑	3楼
Very Rapid Preparation of SmI2 by Sonic Treatment of Iodoform and Metallic Samarium,

回复人：rrrzzz,▲ (学生) 时间：2006-03-17 22:52:09 编辑	4楼
已经打分了。

得分人：tangyyer-2,chemsolve-1,

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