定制各类格氏试剂

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版块:有机化学问题(jimuwei,fpcwin1211,netpanda,yjgzfl,Ftian,)
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时间:2006-03-22 21:17:02  编辑    加入/取消收藏    订制/取消短消息    举报该贴    

盐酸羟亚胺的英文名,分子式,CAS编号以及各理化特征
回复人:dfcpkfzx,▲▲▲ (从化学到化工) 时间:2006-03-22 21:27:59   编辑 1楼
盐酸羟亚胺
咖啡黄色结晶粉末状
含量,(%) 99.6
熔点,(℃) 174~180℃
干燥失重,(%) <0.5
重金属含量,(mg/l) <20
灰分,(%) <0.03
水份,(%) <0.03

包 装:黄色纸板桶装,内衬PE薄膜袋。25kg/桶



回复人:飘逸雪, (将天然有机产物的合成做为艺术的一个合成人) 时间:2006-03-22 21:38:53   编辑 2楼
已经给你了
Language: EN
Country:

**** MATERIAL SAFETY DATA SHEET ****

3-Amino-1H-1,2,4-triazole, 95%

**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****

MSDS Name: 3-Amino-1H-1,2,4-triazole, 95%
Catalog Numbers:
26457-0000, 26457-1000
Synonyms:
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
| 61-82-5 |3-Amino-1H-1,2,4-triazole | 95% | 200-521-5 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Hazard Symbols: XN N
Risk Phrases: 40 48/22

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Limited evidence of a carcinogenic effect. Harmful : danger of
serious damage to health by prolonged exposure if swallowed. Toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

Potential Health Effects
Eye:
May cause mild eye irritation.
Skin:
May cause mild skin irritation. May be harmful if absorbed through
the skin.
Ingestion:
Harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Limited evidence of a carcinogenic effect.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment

Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Flakes
Color: white - green - yellow
Odor: Not available.
pH: 6.5-7.5 (10% aq.sol.)
Vapor Pressure: 0.1hPa @20 deg C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 149 - 156 deg C
Autoignition Temperature: 225 deg C ( 437.00 deg F)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 280 g/l (20?C)
Specific Gravity/Density:
Molecular Formula: C2H4N4
Molecular Weight: 84.08

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, acid chlorides, aluminum,
copper, iron, acid anhydrides, iron salts.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 61-82-5: XZ3850000
LD50/LC50:
CAS# 61-82-5: Oral, mouse: LD50 = 14700 mg/kg; Oral, rat: LD50 =
1100 mg/kg; Skin, rat: LD50 = >10 gm/kg.
Carcinogenicity:
3-Amino-1H-1,2,4-triazole -
ACGIH: A3 - Animal Carcinogen
California: carcinogen; initial date 7/1/87
NIOSH: potential occupational carcinogen
NTP: Suspect carcinogen
OSHA: Possible Select carcinogen
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish toxicity : 96 hr, LC50 : mosquito fish : 2100 mg/l (Johnson;
Proc.Roy.Soc. Queensland 1978)48 hr, LC50 : Silver Salmon 325 mg/l
(Bond, C.E. R.A. Saft.San.Eng.Cen.Tech.Rep. 1960)48 hr, LC50 :
bluegill s. >180 mg/l (Robertson, Govt.Rep.An. 1975)2 hr, LC50 :
whitebait 0.45% Corresponding to active ingredient conc. of 26 mg/l
(Gillespie, Environ.Toxicol.Chem.1989 (= 1))Invertebrate toxicity :
Mud crab, 4hr : direct spray full str. mixt. no montality (1)EC50,
5-30 min : Photobact. ph. 180-582 mg/l Microtox test (Kaiser,Water
Pollut.Res.J.Can 1991)Water-Danger/Protection : WGK 2

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
*
Hazard Class: 9
UN Number: 3077
Packing Group: III
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class: 9
UN Number: 3077
Packing Group: III
RID/ADR
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class: 9
UN Number: 3077
Packing group: III
USA RQ:CAS# 61-82-5: 10 lb final RQ; 4.54 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 40 Limited evidence of a carcinogenic effect.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 36 Wear suitable protective clothing.
S 37 Wear suitable gloves.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 61-82-5: 2
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
CAS# 61-82-5 is listed on Canada's DSL List.
CAS# 61-82-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 61-82-5: OEL-AUSTRALIA:TWA 0.2 mg/m3
OEL-AUSTRIA:TWA 0.2 mg/m3
OEL-BELGIUM:TWA 0.2 mg/m3
OEL-DENMARK:TWA 0.2 mg/m3;Carcinogen
OEL-FINLAND;Carcinogen
OEL-GERMANY:TWA 0.2 mg/m3
OEL-THE NETHERLANDS:TWA 0.2 mg/m3
OEL-SWITZERLAND:TWA 0.2 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 61-82-5 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 7/16/1996 Revision #1 Date: 3/02/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------



回复人:飘逸雪, (将天然有机产物的合成做为艺术的一个合成人) 时间:2006-03-22 21:40:33   编辑 3楼
你上
http://www.chemexper.com/
然后Triazolam就可以了





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