问题：Comprehensive Organic Functional Group Transformations II, V. 6
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时间：2006-07-29 07:35:18 编辑加入/取消收藏订制/取消短消息举报该贴

Title: Comprehensive Organic Functional Group Transformations II,
Volume 6: Carbon with Three or Four Attached Heteroatoms
Edited by E.F.V. Scriven, University of Florida, Gainesville, FL, USA

Description
Volume 6 is in four parts. Part I deals with tetracoordinate carbons bearing three heteroatoms. Part II covers tetracoordinate compounds bearing four heteroatoms, i.e. substituted methanes, and Part III deals with tricoordinate systems bearing three heteroatoms, i.e. where one heteroatom is attached by a double bond. Part IV is brief and deals with stabilized radicals and ions. Not surprisingly, the coverage of Volume 6 is very large - and also indicates that many gaps in the development of organic chemistry still exist.

The organization within the three sections not only follows the same broad logic developed in the previous volumes, but also has a structure unique to this multiheteroatom volume. According to the Latest Placement Principle, CF3C(NR2)3 appears in the section dealing with carbons bearing three nitrogens (6.05.1.1), not that dealing with carbons bearing three halogens (6.01.2), while (CF3CH2O)2CO appears in Part III, not in Part I.

In the chapter dealing with iminocarbonyl functions in Part III, the substituents on nitrogen are discussed in each appropriate subsection in the order outlined above. Thus, the RN: group would be first considered with R = H, then alkyl, alkenyl, aryl and hetaryl, alkynyl and then heteroatom substituents in the usual order.

In each of the relevant sections, we have endeavored to explain the influence of important secondary effects on the synthesis such as structure (primary, secondary, etc), ring effects, strain, activation, stereochemistry, remote substituent effects, etc.
The arrangement of the chemistry in each of Parts I-III follows a similar pattern. Thus, each section commences with functions containing at least one halogen. This section deals with all combinations of halogen with other heteroatoms in the described order. The next section deals with functions containing at least one chalcogen in combination with any other heteroatoms except halogens. Subsequent sections each exclude the previous title heteroatom functions.

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回复人：yjgzfl,★ (研究) 时间：2006-07-30 10:46:00 编辑	1楼
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回复人：zhiyi,▲ (非常乐意认识化工界的各位朋友) 时间：2006-08-08 16:14:02 编辑	2楼
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