问题：苯并菲的合成工艺
类型：求助 (悬赏分:3分)
提问：ihongyu
等级：▲
版块：有机化学问题(jimuwei,fpcwin1211,netpanda,yjgzfl,Ftian,)
信誉：20%
回复：4
阅读：717
时间：2006-11-18 14:49:09 编辑加入/取消收藏订制/取消短消息举报该贴

谁能提供苯并菲的合成工艺
imhongyu@163.com
谢谢

回复人：tangyyer,★★★★★ (有空来逛逛my blog: http://tangyyer.blog.hexun.com) 时间：2006-11-18 17:01:32 编辑	1楼
应该可以用格氏试剂来作。

回复人：ihongyu,▲ () 时间：2006-11-18 20:02:38 编辑	2楼
用什么原料

回复人：haozhenwen,▲ (化学人一个) 时间：2006-11-19 17:50:32 编辑

3楼

Entry Name: 7H-Benzo[c]fluorene
Synonym(s): 3,4-
2821560,339

Chapman Hall Number: FMN82-T
CAS Registry Number: 205-12-9

Molecular Formula: C17H12
Molecular Weight: 216.282
Accurate Mass: 216.0939
Percentage Composition: C 94.41%; H 5.59%
Source/Synthesis: Constit. of coal tar. Widespread environmental pollutant. Present in tobacco smoke, automobile exhaust and other sources
Physical Description: Plates (EtOH)
Melting Point: Mp 124-125
Hazard Toxicity: Carcinogen. Potent inducer of lung tumours in mice
RTECS Accession Number: DK6384000
RCB_CT,48462Derivative: Picrate
Chapman Hall Number: FMN83-U
Physical Description: Red needles (EtOH)
Melting Point: Mp 130-131
References:
Cook, J.W. et al., J.C.S., 1935, 1319, (synth)
Keene, B.R.T. et al., J.C.S., 1958, 1080, (synth)
Jones, D.W. et al., Spectrochim. Acta A, 1972, 28, 2053, (pmr)
IARC Monog., 1983, 32, 189; Suppl. 7, 58, (rev, tox)
Harvey, R.G. et al., J.O.C., 1991, 56, 1210, (synth, pmr)
Wang, J.-Q. et al., J.O.C., 2002, 67, 6216-6219, (activity, bibl)

回复人：ihongyu,▲ () 时间：2006-11-19 21:47:08 编辑	4楼
哪能下到这些文献

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