问题：找个核磁谱图
类型：求助 (悬赏分:3分)
提问：scx235
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版块：有机化学问题(jimuwei,fpcwin1211,netpanda,yjgzfl,Ftian,)
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时间：2005-04-22 21:05:20 编辑加入/取消收藏订制/取消短消息举报该贴

问问各路大侠在那可以查物质的核磁谱图？我想查一下1，10-菲罗林；1，10-phenanthroline的ＮＭＲ？

回复人：zhixiangch,▲▲▲▲ (希望来这里和大家交朋友，相互交流和学习知识。) 时间：2005-04-22 21:49:34 编辑

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&chev; Synonym(s): o - Phenanthroline . Phen. 4,5-Diazaphenanthrene Chapman and Hall Number: FZK59-P CAS Registry Number: 66-71-7 Related CAS Registry Numbers(s): 5144-89-8 Extra CAS Registry Numbers(s): 12678-01-2 Type of Compound Code(s): PS8300 PM6150 PA2000 Molecular Formula: C 12 H 8 N 2 Molecular Weight: 180.209 Accurate Mass: 180.068748 Percentage Composition: C 79.98%; H 4.47%; N 15.54% Use/Importance: Used as soln. in dil. HCl for photometric detn. of Fe( II ) (lambda max 512 nm, epsi 11000); chelating agent for Zn, Cd, Co, Ni, Ag, Ru, Os; counter-ion in extn. of anionic complexes (e.g. Ge, Co, Ru) Physical Description: Cryst. + 1H 2 O (H 2 O), cryst. (C 6 H 6 ) Melting Point: Mp 98-100degrees (93-94degrees) pKa Value: p K a 4.92 (25degrees, 0.1 M KNO 3 ) Hazard and Toxicity: LD 50 (mus, ipr) 75 mg/kg. Exp. teratogen RTECS Accession Number: SF8300000 Aldrich: 13137-7 Derivative: Hydrochloride Chapman and Hall Number: MJJ56-Y CAS Registry Number: 3829-86-5 Extra CAS Registry Numbers(s): 18851-33-7 Physical Description: Cryst. + 1H 2 O Melting Point: Mp 224-225 dec.degrees Aldrich: P1300-2 Fluka: 77510 Derivative: N -Oxide Chapman and Hall Number: FZK63-M CAS Registry Number: 1891-19-6 Molecular Formula: C 12 H 8 N 2 O Molecular Weight: 196.208 Accurate Mass: 196.063663 Percentage Composition: C 73.46%; H 4.11%; N 14.28%; O 8.15% Physical Description: Pale yellow needles (PhCl) Melting Point: Mp 180-181degrees pKa Value: p K a 6.63 (22degrees) Derivative: N , N '-Dioxide Chapman and Hall Number: FZK64-N CAS Registry Number: 72799-24-7 Molecular Formula: C 12 H 8 N 2 O 2 Molecular Weight: 212.207 Accurate Mass: 212.058578 Percentage Composition: C 67.92%; H 3.80%; N 13.20%; O 15.08% Physical Description: Cryst. (EtOH aq.) Melting Point: Mp 200degrees Other Data: Contains a non-planar phenanthroline skeleton References: Aldrich Library of FT-IR Spectra, 1st edn. , 1985, 1 , 889D; 2 , 889D; 890B, (ir) Aldrich Library of 13C and 1H FT NMR Spectra , 1992, 3 , 474C; 475A, (nmr) Smith, C.R. , J.A.C.S. , 1930, 52 , 397-403, (synth) Smith, C.R. et al. , Chem. Rev. , 1935, 16 , 113-120, (synth) Willink, H.D.T. et al. , Rec. Trav. Chim. (J. R. Neth. Chem. Soc.) , 1935, 54 , 275-283, (synth) Harvey, A.E. et al. , Anal. Chem. , 1955, 27 , 26-29, (detn, Fe) Hibbits, J.O. et al. , Talanta , 1961, 8 , 163-164, (detn, Fe) Corey, E.J. et al. , J.O.C. , 1965, 30 , 288-290, (oxide) Schilt, A.A. , Analytical Applications of 1,10-Phenanthroline and Related Compounds , Pergamon, Oxford, 1969 Budzikiewicz, H. et al. , Z. Naturforsch., B , 1970, 25 , 178-180, (ms) Nishigaki, S. et al. , Acta Cryst. B , 1975, 31 , 1220, (cryst struct) Holzbecher, Z. , Handbook of Organic Reagents in Inorganic Analysis , Horwood, Chichester, 1976 Summers, L.A. , Adv. Heterocycl. Chem. , 1978, 22 , 1-69, (rev) Koennecke, A. et al. , Org. Magn. Reson. , 1979, 12 , 696-701, (cmr) Cheng, K.L. et al. , Handbook of Organic Analytical Reagents , CRC Press, Boca Raton, 1982 Engbersen, J.F.J. et al. , J. Het. Chem. , 1986, 23 , 989-990, (oxide) Marczenko, Z. , Separation and Spectrophotometric Determination of Elements , Horwood, Chichester, 1986 Thornton, D.A. et al. , Spectrochim. Acta A , 1991, 47 , 1085-1096, (ir, Raman) Sammes, P.G. et al. , Chem. Soc. Rev. , 1994, 23 , 327-334, (rev) Rozen, S. et al. , Angew. Chem., Int. Ed. , 1999, 38 , 3472-3473, (dioxide, synth, ir, uv, pmr, cmr, cryst struct) Sigma-Aldrich Library of Stains, Dyes and Indicators , 557; 560 Lewis, R.J. , Sax's Dangerous Properties of Industrial Materials, 8th edn., Van Nostrand Reinhold , 1992, PCY250

回复人：zhixiangch,▲▲▲▲ (希望来这里和大家交朋友，相互交流和学习知识。) 时间：2005-04-22 21:50:57 编辑	2楼
核磁的我没有，CCD上的我给你查了一下。

回复人：shwh,▲▲ () 时间：2005-04-22 21:51:17 编辑	3楼
有aldrich的NMR谱图,但怎么给你?

回复人：zhanghx88,★ () 时间：2005-04-22 23:32:30 编辑	4楼
见 http://www.ccebbs.com/forum/dispq.asp?lid=26504

回复人：Yan,★ (他山之石，可以攻玉) 时间：2005-04-23 07:36:48 编辑	5楼
接受答案了。

回复人：scx235,▲ () 时间：2005-04-23 22:10:55 编辑	6楼
谢谢zhanghx88-2

回复人：brillfan,▲ (创造的美) 时间：2005-05-20 22:00:48 编辑	7楼
http://www.aist.go.jp/RIODB/SDBS/cgi-bin/direct_frame_top.cgi?lang=eng

得分人：zhanghx88-2,

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