问题：跪求文献。。。一定加高分！
类型：求助 (悬赏分:3分)
提问：ziyan
等级：▲
版块：有机化学问题(jimuwei,fpcwin1211,netpanda,yjgzfl,Ftian,)
信誉：60%
回复：8
阅读：742
时间：2007-08-14 22:15:24 编辑加入/取消收藏订制/取消短消息举报该贴

1.Solid-gel precursor solutions and methods for the fabrication of polymetallosiloxane coating films.
U.S. (1992), 15 pp. CODEN:USXXAM; US5110863
2.Oxidation of alkenes with hydrogen peroxide catalyzed by iron porphyrins immobilized to imidazole groups in a hydrophobic environment on a modified silica surface.
Bulletin of the Chemical Society of Japan (1993), 66, (8), 2385-90. CODEN:BCSJA8 ISSN:0009-2673.
3.N-Trialkoxysilylpropylimidazoles.
Czech. (1982), 2 pp. CODEN:CZXXA9; CS195648

回复人：jidanhun,▲▲ (吡啶类氯化技术,领会中……) 时间：2007-08-16 14:19:59 编辑	1楼
是不是这个，我发给你？

回复人：jidanhun,▲▲ (吡啶类氯化技术,领会中……) 时间：2007-08-16 16:23:39 编辑	2楼
但是第三个专利不好查，是捷克斯洛伐克

回复人：jidanhun,▲▲ (吡啶类氯化技术,领会中……) 时间：2007-08-16 14:19:18 编辑

3楼

Solutions and preparation methods necessary for the fabrication of metal oxide cross-linked polysiloxane coating films are disclosed. The films are useful in provide heat resistance against oxidation, wear resistance, thermal insulation, and corrosion resistance of substrates. The sol-gel precursor solution comprises a mixture of a monomeric organoalkoxysilane, a metal alkoxide M(OR).sub.n (wherein M is Ti, Zr, Ge or Al; R is CH.sub.3, C.sub.2 H.sub.5 or C.sub.3 H.sub.7 ; and n is 3 or 4), methanol, water, HCl and NaOH. The invention provides a sol-gel solution, and a method of use thereof, which can be applied and processed at low temperatures (i.e., <1000.degree. C.). The substrate can be coated by immersing it in the above mentioned solution at ambient temperature. The substrate is then withdrawn from the solution. Next, the coated substrate is heated for a time sufficient and at a temperature sufficient to yield a solid coating. The coated substrate is then heated for a time sufficient, and temperature sufficient to produce a polymetallicsiloxane coating.

回复人：jidanhun,▲▲ (吡啶类氯化技术,领会中……) 时间：2007-08-16 14:20:24 编辑	4楼
Solid-gel precursor solutions and methods for the fabrication of polymetallicsiloxane coating films

回复人：jidanhun,▲▲ (吡啶类氯化技术,领会中……) 时间：2007-08-16 14:24:46 编辑	5楼
其他的两个实在不好查，一个好像是捷克斯洛伐克的文献

回复人：yan,★ (他山之石，可以攻玉) 时间：2007-08-16 14:33:48 编辑	6楼
1，3是专利，到这里肯定可以查第1篇。 http://ep.espacenet.com/

回复人：幼儿园水平,▲ (№◆△←◇＆◇■＿＃←◇) 时间：2007-08-16 20:31:37 编辑	7楼
真不简单啊

回复人：ziyan,▲ (共同交流,共同进步!) 时间：2007-08-16 22:10:13 编辑	8楼
谢谢大家的支持和帮助阿。

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