问题：求助：请问有哪位知道异丙醇钛是怎么合成的？
类型：求助 (悬赏分:3分)
提问：dfl0620
等级：▲
版块：元素及金属有机(方无忧,seaword,)
信誉：0%
回复：6
阅读：906
时间：2008-10-15 21:59:29 编辑加入/取消收藏订制/取消短消息举报该贴

因实验需要，请求大家帮忙告知一下异丙醇钛的合成步骤，谢谢大家！

回复人：tangyyer,★★★★★ (有空来逛逛my blog: http://tangyyer.blog.hexun.com) 时间：2008-10-15 22:24:46 编辑

1楼

Titanium (IV) isopropoxide
CAS：546-68-9
Form: Liquid
Color: Light yellow
Odor: Alcohol-like
Melting point/Melting range: 18-20 ° C
Boiling point/Boiling range: 220 ° C

更具体的性质：
Property Value Condition Note
Boiling Point 220 癈 SRC
Boiling Point 220 癈 Press: 760 Torr NLM
13C NMR Spec See full text (1) CAS
13C NMR Spec See full text (2) CAS
13C NMR Spec See full text (3) CAS
13C NMR Spec See full text (4) CAS
Cryst Lattice Param See full text (5) CAS
Density 0.9711 g/cm3 Temp: 20 癈 NLM
IR Absorp Spec See full text (2) CAS
IR Absorp Spec See full text (6) CAS
IR Absorp Spec See full text (7) CAS
IR Absorp Spec See full text (8) CAS
IR Absorp Spec See full text (9) CAS
Mass Spectrum See full text (1) CAS
Mass Spectrum See full text (4) CAS
Melting Point 218-220 癈 (4) CAS
Melting Point 20 癈 (approx) NLM
Melting Point 20 癈 SRC
Optical Rotatory Power -27.5 ?Conc: 0.73 (2) CAS
g/100mL
Solv: chloroform
(67-66-3)
Wavlen: 589.3
nm
Optical Rotatory Power -80 ?Conc: 0.10 (4) CAS
g/100mL
Solv: chloroform
(67-66-3)
Wavlen: 589.3
nm
Temp: 22 癈
31P NMR Spec See full text (1) CAS
Particle Size See full text (5) CAS
Proton NMR Spectrum See full text (2) CAS
Proton NMR Spectrum See full text (4) CAS
Proton NMR Spectrum See full text (3) CAS
Proton NMR Spectrum See full text (1) CAS
Refractive Index 1.46 NLM
Thermal Expan Coeff See full text (5) CAS
UV-Vis Absorp Spec See full text (8) CAS
Vap Press/Volatility See full text (10) CAS
X-Ray Absorp Spec See full text (5) CAS
X-Ray Diff Pattern See full text (5) CAS
X-Ray Diff Pattern See full text (11) CAS

Notes:
(1) Morgan, John P.; Chemical Communications (Cambridge, United Kingdom) 2005, (26), P3307-3309
(2) dos Santos, Anderson Rouge; European Journal of Organic Chemistry 2005, (15), P3348-3359
(3) Belda, Oscar; Journal of Organometallic Chemistry 2004, V689(23), P3750-3755
(4) Song, Zhiguo J.; Proceedings of the National Academy of Sciences of the United States of America 2004, V101(16), P5776-5781
(5) Jagtap, Neelam; Thermochimica Acta 2005, V427(1-2), P37-41
(6) Nunes, Giovana G.; New Journal of Chemistry 2002, V26(5), P519-522
(7) Beyrhouty, Mirvat; New Journal of Chemistry 2005, V29(10), P1245-1248
(8) Sakuraba, Hidetake; Shikizai Kyokaishi 2003, V76(4), P138-141
(9) Zhou, Xing-fu; Anhui Shifan Daxue Xuebao, Ziran Kexueban 2001, V24(3), P228-230
(10) Li, Tingkai; EP 1184485 A1 2002
(11) Liu, Ping; Wuji Huaxue Xuebao 2003, V19(4), P350-354

回复人：zhounengya,▲ (我来了……) 时间：2008-10-31 11:25:30 编辑	2楼
什么啊？！

回复人：trotk,▲ (一个爱学问的人) 时间：2009-07-29 08:31:24 编辑	3楼
建议你看汪联辉的一篇文章，里面有，希望有帮助。

回复人：zhaoqy03,▲ () 时间：2009-09-26 20:52:29 编辑	4楼
我不知道lz是否是做多所大量的。价格不贵的，我们实验室一直买的。

回复人：zhaoqy03,▲ () 时间：2009-09-26 20:52:32 编辑	5楼
我不知道lz是否是做多所大量的。价格不贵的，我们实验室一直买的。

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2009-09-26 21:08:53 编辑	6楼
已经打分了！

得分人：tangyyer :1, trotk :1, zhaoqy03 :1,

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