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问题:急求CA,会查的帮我下
类型:求助 (悬赏分:3分)
提问:ykaii
等级:
版块:文献检索技术、各类代理(wguoyong,wangjinyon,)
信誉:40%
回复:2
阅读:437
时间:2009-06-09 09:35:28  编辑    加入/取消收藏    订制/取消短消息    举报该贴    

我前几天查CA漏了一段话,CA: 112:56218a 看的懂的速度帮我下忙哦【Synthesis and crystal structure of (η5-C5H5)NiF=e3(CO)7(μ-PPh2)(μ4,η2-HC≡CCHMe2):a butterfly cluster with an unprecedented metal core stoichiometry.Sappa,Enrico;Belletti,Daniele;Tiripicchio,Antonio;Camellini,Marisa Tiripicchio(Dip.Chim.Inorg.Chim.Fis.Chem.Mater.,Univ.Torino,10125 Turin, Italy).J.Organomet.Chem.1989,359(3),419-28(Eng).The reaction of Fe2(CO)9 or Fe3(CO)12 with (Cp)2Ni2(Ph2PC≡CR)(R=CHMe2,Ph;Cp=η5-cyclopentadienyl) leads to several heterometallic clusters with known or unprecedented structures. The complexes (Cp)NiFe2(CO)6(μ3,η2-C2R),(Cp)2Ni2Fe2(CO)6(μ4,η2-HC≡CR),(Cp)2Ni2Fe2(CO)5(μ-PPh2)(μ4,η2-C2R),(Cp)2NiFe2(CO)3(μ-PPh2)(C2R) and (Cp)NiFe3(CO)7(μ-PPh2)(μ4,η2-HC≡CR) (I) were identified in the reaction mixts.】后面还有一段话
回复人:claymore,★★★★★ (C-H活化,kumada,suzuki,stille,negishi.cross-coupling.) 时间:2009-06-09 10:17:37   编辑 1楼
【题名】Synthesis and crystal structure of (η5-C5H5)NiFe3(CO)7(μ-PPh2)(μ4,η2-HCCPri): a butterfly cluster with an unprecedented metal core stoichiometry
【作者】Enrico Sappa, Danielle Belletti, Antonio Tiripicchio, Marisa Tiripicchio Camellini
【杂志名全称】Journal of Organometallic Chemistry
【年, 卷(期), 起止页码】Volume 359, Issue 3, 17 January 1989, Pages 419-428
【全文链接】http://www.box.net/shared/7e91c8oxkf


一篇小小的文献,还要这么大动干戈啊?还要请专业老师,呵呵


回复人:ykaii, () 时间:2009-06-09 13:32:56   编辑 2楼
呵呵,那你还知道有哪些合成二茂镍的方法吗?(最好是中文的)我在网上还难找


得分人:claymore :3,


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