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问题:关于丁基锂的kinetic basicity
类型:求助 (悬赏分:3分)
提问:黄十字
等级:▲▲
版块:元素及金属有机(方无忧,seaword,)
信誉:93%
回复:2
阅读:708
时间:2009-12-13 19:41:39  编辑    加入/取消收藏    订制/取消短消息    举报该贴    

The kinetic basicity of n-BuLi is affected by the reaction solvent or cosolvent. Ligands that complex Li+ such as tetrahydrofuran (THF), tetramethylethylenediamine (TMEDA), hexamethylphosphoramide (HMPA), and 1,4-diazabicyclo[2.2.2]octane (DABCO) further polarize the Li-C bond and accelerate the metalation. Such additives can also aid in the isolation of the lithiated product, a famous example of which is dilithioferrocene.

请问文中的kinetic basicity (动力学碱性)到底怎么理解?
回复人:admin, (论坛管理员-欢迎大家访问化学化工论坛) 时间:2009-12-14 07:25:56   编辑 1楼
kinetic: Of, relating to, or produced by motion.

motion: The act or process of changing position or place.

翻译成汉语真是一件困难的事情。

位置改变的碱性?


回复人:黄十字,▲▲ (实事求是!如果做不到,就承认做不到;如果承诺了,就一定要做到!) 时间:2010-03-01 20:59:47   编辑 2楼
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