问题：Chem. Abstr
类型：求助 (悬赏分:18分)
提问：Ftian
等级：★★
版块：文献代查(hipbird,playdoom,claymore,)
信誉：100%
回复：10
阅读：3290
时间：2010-02-01 11:39:12 编辑加入/取消收藏订制/取消短消息举报该贴

【题名】
【作者】S. A. Harris,
【杂志名全称】Chem.Abstr
【年,卷(期),起止页码】27, 279 (1933).
【DOI】
【全文链接】
【求助者email】
qinw_wd@163.com

如果有电子版的最好......
如果短的,帮我抄下来,也可以的.
用手机照的图片也可以的,但希望清晰可见.

谢谢帮忙的好心人.

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-02-01 11:55:49 编辑	1楼
图书馆吧

回复人：Ftian,★★ (资料请发到我的邮箱里，这里封纳米盘。) 时间：2010-02-01 13:14:53 编辑	2楼
是的.我现在不在学校了...没办法啊.

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-02-07 14:35:51 编辑	3楼
abnormal reaction of organometalli compound A The abnormal reaction of cinnamyl chloride with magnesium Stanton A Harris

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-02-07 14:43:02 编辑

4楼

The grinard reagent prepd. by adding cinnamyl chloride in 15mol. equiv. of ether to 6 at.equivs of 30-60 mesh Mg acted as though its structrue is Ph-CH(MgCL)CH:CH2. With CO2, PhCH:CH2CO2H was formed;
and with PhNCO,PhCH:CHCH2CONHPh was formed .Accompanying the formation of the Grignard reagent was the formation of bicinnamyl and liquid hydrocarbons. The structure of one of the hydrocarbons is PhCH:CHCH2CHPhCH:CH2, as established by analytical and synthetic process.

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-02-07 14:44:33 编辑	5楼
B Grignard reagent from halogenated tertiary amines .

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-02-07 14:52:36 编辑

6楼

3-Bromopyridine and 3,5-dibromopyridine do not form Grignard reagent when cold . They form tars at higher temps. and during the reaction a color test for Grignard reagent with Michler's ketone is produced.
2-Iodopyridine reacts with Mg to form a green soln .and an insol .tar .
The soln. gives no color test with Michler's ketone ,but if the ketone is added immediately to the soln.and tar the color test is pos.o-IC6H4NMe2 and o-BrC6H4NMe2 gives high yields of Grignard reagents in the presence of I2 as a catalyst .

F.E.BROWN.

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-02-07 14:53:12 编辑	7楼
你报销我车费加复印费吗?

回复人：Ftian,★★ (资料请发到我的邮箱里，这里封纳米盘。) 时间：2010-02-08 14:10:19 编辑	8楼
谢谢了.感动啊.我想给你报销的.

回复人：Ftian,★★ (资料请发到我的邮箱里，这里封纳米盘。) 时间：2010-02-08 14:10:32 编辑	9楼
谢谢了.感动啊.我想给你报销的.

回复人：Ftian,★★ (资料请发到我的邮箱里，这里封纳米盘。) 时间：2010-02-08 14:10:50 编辑	10楼
谢谢了.感动啊.我想给你报销的.

得分人：claymore :18,

问题讨论没有结束...

您尚未进入本论坛,登录之后才可以回贴

7msec