问题：求两个物质的物化性质
类型：求助 (悬赏分:3分)
提问：yunjinqi
等级：▲▲
版块：文献检索技术、各类代理(wguoyong,wangjinyon,)
信誉：94%
回复：6
阅读：624
时间：2010-06-01 12:29:39 编辑加入/取消收藏订制/取消短消息举报该贴

各位大侠，我想拜托高手帮我查到下面两个物质的物化性质，特别是沸点。
CAS 13116-57-9
CAS 13116-58-0
谢谢！有资料请发到 xuanhuawwf@sina.com

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-06-19 07:36:56 编辑

1楼

你们别自己不懂,就老说查不到

Experimental Property Values

Registry Number: 13116-57-9

Double bond geometry as shown.
_

Formula: C3 H3 Cl3

CA Index Name: 1-Propene, 1,2,3-trichloro-, (1Z)-

Property Value Condition Note
Boiling Point 136.2-137.2 癈 (1) CAS
Boiling Point 87 癈 Press: 100 Torr (2) CAS
Boiling Point 85 癈 Press: 100 Torr (3) IC
Carbon-13 NMR See spectrum (4) WSS
Spectrum
Carbon-13 NMR See spectrum (5) WSS
Spectrum
Carbon-13 NMR See spectrum (5) WSS
Spectrum
Carbon-13 NMR See spectrum (5) WSS
Spectrum
Density 1.4238 g/cm3 Temp: 425 癈 (2) CAS
Density 1.4020 g/cm3 Temp: 20 癈 (3) IC
Density 1.4019 g/cm3 Temp: 20 癈 (1) CAS
Mass Spectrum See spectrum (4) WSS
Proton NMR Spectrum See spectrum (6) AIST
Proton NMR Spectrum See spectrum (6) AIST
Proton NMR Spectrum See full text (3) IC
Refractive Index 1.5020 Wavlen: 589.3 (2) CAS
nm
Temp: 25 癈
Refractive Index 1.5000 Temp: 20 癈 (3) IC
Refractive Index 1.4995 Wavlen: 589.3 (2) CAS
nm
Temp: 30 癈
Refractive Index 1.4984 Wavlen: 589.3 (1) CAS
nm
Temp: 20 癈

Notes:
(1) Hearne, G. W.; Journal of the American Chemical Society 1953, V75, P1392-4
(2) Hatch, Lewis F.; Journal of the American Chemical Society 1952, V74, P123-6
(3) Mel'nikova, N. B.; Zhurnal Organicheskoi Khimii 1980, V16(10), P2026-32
(4) WSS: Spectral data were obtained from Wiley Subscription Services, Inc. (US)
(5) Chukovskaya, E. C.; Organic Magnetic Resonance 1976, V8(5), P229-32
(6) AIST: Integrated Spectral Database System of Organic Compounds. (Data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan))

Database: REGISTRY

回复人：jimuwei,★★★ () 时间：2010-06-05 10:40:50 编辑	2楼
没有找到相关物质，是不是先核对CAS号!

回复人：lilibaobei,▲ (从事化工研究的一员) 时间：2010-06-19 06:50:06 编辑	3楼
没有该物质，

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-06-19 07:37:31 编辑	4楼
癈为乱码 ,度的意思

回复人：claymore,★★★★★ (C-H活化，kumada,suzuki,stille,negishi.cross-coupling.) 时间：2010-06-19 07:39:31 编辑

5楼

Experimental Property Values

Registry Number: 13116-58-0

Double bond geometry as shown.
_

Formula: C3 H3 Cl3

CA Index Name: 1-Propene, 1,2,3-trichloro-, (E)- (9CI)

Property Value Condition Note
Boiling Point 78 癈 Press: 100 Torr (1) IC
Boiling Point 75 癈 Press: 100 Torr (2) CAS
Boiling Point 75.0 癈 (2) CAS
Boiling Point 32-33 癈 Press: 14 Torr (3) CAS
Carbon-13 NMR See spectrum (4) WSS
Spectrum
Carbon-13 NMR See spectrum (5) WSS
Spectrum
Density 1.4060 g/cm3 Temp: 20 癈 (1) IC
Density 1.4057 g/cm3 Temp: 25 癈 (2) CAS
Density 1.402 g/cm3 Temp: 16 癈 (3) CAS
Proton NMR Spectrum See spectrum (6) AIST
Proton NMR Spectrum See spectrum (6) AIST
Proton NMR Spectrum See full text (1) IC
Refractive Index 1.4993 Wavlen: 589.3 (3) CAS
nm
Temp: 16 癈
Refractive Index 1.4956 Wavlen: 589.3 (2) CAS
nm
Temp: 25 癈
Refractive Index 1.4932 Wavlen: 589.3 (2) CAS
nm
Temp: 30 癈
Refractive Index 1.4920 Temp: 20 癈 (1) IC
Refractive Index 1.4460 Wavlen: 589.3 (2) CAS
nm
Temp: 25 癈

Notes:
(1) Mel'nikova, N. B.; Zhurnal Organicheskoi Khimii 1980, V16(10), P2026-32
(2) Hatch, Lewis F.; Journal of the American Chemical Society 1952, V74, P123-6
(3) Kirrmann, Albert; Bulletin de la Societe Chimique de France 1948, P166-8
(4) WSS: Spectral data were obtained from Wiley Subscription Services, Inc. (US)
(5) Chukovskaya, E. C.; Organic Magnetic Resonance 1976, V8(5), P229-32
(6) AIST: Integrated Spectral Database System of Organic Compounds. (Data were obtained from the National Institute of Advanced Industrial Science and Technology (Japan))

Database: REGISTRY

回复人：yunjinqi,▲▲ () 时间：2010-08-06 07:54:52 编辑	6楼
谢谢！

得分人：claymore :3,

问题讨论没有结束...

您尚未进入本论坛,登录之后才可以回贴

8msec