问题：【Chemical Reviews】【Iminium Catalysis】
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Iminium Catalysis

FiguresCiting ArticlesAnniina Erkkilä, Inkeri Majander, and Petri M. Pihko*
Laboratory of Organic Chemistry, Department of Chemical Technology, Helsinki University of Technology, P.O. Box 6100, FI-02015 TKK, Finland
Chem. Rev., 2007, 107 (12), pp 5416–5470
DOI: 10.1021/cr068388p
Publication Date (Web): December 12, 2007
Copyright © 2007 American Chemical Society

1. Introduction
2. Iminium Catalysis
2.1. Iminium Ions

2.2. Historical Development of Iminium Catalysis

2.3 Structure−Activity Relationships

2.4. Structural Studies of Iminium Ions
3. Cycloadditions
3.1. Diels−Alder Reactions3.1.1. Historical Noncatalytic Precedents
3.1.2. Diels−Alder Reactions of Enals
The 3.1.3. Diels−Alder Reactions of Enones
3.1.4. Intramolecular Diels−Alder Reactions
3.1.5. Diels−Alder Reactions Catalyzed by Primary Amines
3.1.6. Applications in Natural-Product Synthesis

3.2. [3+2]-Cycloadditions
4. Conjugate Additions
4.1. Introduction

4.2. C-nucleophiles4.2.1. 1,3-Dicarbonyl Compounds
4.2.2. Nitroalkanes
4.2.3. Aromatic Compounds
4.2.4. Silyl Enol Ethers
4.2.5. Other Nucleophiles

4.3. H-Nucleophiles

4.4. S-Nucleophiles

4.5. N-Nucleophiles

4.6. O-Nucleophiles
5. Iminium−Enamine Manifold
6. Domino Processes

6.1. Intramolecular Domino Reactions6.1.1. Three-Membered Rings
6.1.2 Five-Membered Rings
6.1.3. Six-Membered Rings
6.1.4. Other Ring Sizes

6.2. Intermolecular Domino Reactions
7. Iminium-Catalyzed Reactions of Saturated Carbonyl Compounds

7.1. Transamination

7.2. Iminium Catalysis Followed by Elimination of the Amine7.2.1. Knoevenagel Condensations
7.2.2. Knoevenagel−Mannich

7.3. Cleavage of C−X α-Bond

7.4. Other Iminium-Catalyzed Reactions
8. Conclusions
9. Abbreviations
10. Acknowledgements
11. References

http://d.namipan.com/d/Iminium+Catalysis.pdf/890da8e09baceaa98eb43b409e4dd377db5e253cbdf51c00

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