问题：请帮忙查一个化合物的合成方法
类型：求助 (悬赏分:3分)
提问：gk1996
等级：▲
版块：文献代查(hipbird,playdoom,claymore,)
信誉：100%
回复：2
阅读：562
时间：2011-07-29 11:45:46 编辑加入/取消收藏订制/取消短消息举报该贴

CAS：66710-66-5
英文名：N,N'-Bis(vinylsulfonylacetyl)ethylenediamine
分子式：C10H16N2O6S2
请帮忙查一下合成的文献。谢谢！
邮箱：jazkang@126.com

回复人：qdlct2002,▲▲▲▲ (澳大利亚--我的梦想家园！) 时间：2011-07-29 12:02:04 编辑

1楼

CAN
136:200012

TITLE
One-step preparation of vinylsulfones from (hydroxyalkyl)sulfones.

AUTHOR(S)
Tamura, Atsushi; Miya, Shigemitsu

CORPORATE SOURCE
Wako Pure Chemical Industries, Ltd., Japan

SOURCE
Jpn. Kokai Tokkyo Koho JP 2002060379 A2 26 Feb 2002, 18 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: ICM: C07C315-04. ICS: C07C317-08; C07C317-14; C07C317-44; C07D251-04; C07D251-06; C07D251-24; C07D295-08; C07D317-46; C07B061-00. APPLICATION: JP 2001-154715 24 May 2001. PRIORITY: JP 2000-169896 7 Jun 2000. DOCUMENT TYPE: Patent

CA SECTION/CROSS-REFERENCE(S)
CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) Section cross-reference(s): 21

ABSTRACT
Compds. having R1R2C:CR3T1SO2 groups [T1 = bond, lower alkylene; R1-R3 = H, lower alkyl; R1CCR3 may form (un)substituted alicyclic ring (condensed with arom. or heterocyclic ring)] are prepd. by treatment of compds. having the corresponding HOCR1R2CHR3T1SO2 groups (T1, R1-R3 = same as above) with R4N:C:NR5 (R4, R5 = alkyl). Thus, 4-MeC6H4SO2CH2CH2OH was treated with DCC and FeCl2 at 80° for 15 h in MeCN to give 78.6% 4-MeC6H4SO2CH:CH2.

KEYWORDS

回复人：gk1996,▲ (精细化工合成数载) 时间：2011-07-29 12:56:00 编辑	2楼
谢谢！

得分人：qdlct2002 :3,

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