问题：烯烃复分解反应方面资料
类型：求助 (悬赏分:3分)
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时间：2005-10-08 17:32:35 编辑加入/取消收藏订制/取消短消息举报该贴

求烯烃复分解反应方面资料,pdf,ppt,word

回复人：**元素,▲▲▲* () 时间：2005-10-08 19:19:45 编辑	1楼
今年诺贝尔化学奖的核心！强力关注中...

回复人：fengyu211,▲▲▲ (有东东共享) 时间：2005-10-09 12:25:24 编辑	2楼
请登陆:http://www.organic-chemistry.org/ 里面有很多详细介绍. NEWS FLASH (05 October 2005) The Nobel Prize in Chemistry 2005 (Link) goes to Yves Chauvin, Robert H. Grubbs and Richard R. Schrock "for the development of the metathesis method in organic synthesis". See: Olefin Metathesis, Ring Closing Metathesis, Recent Literature, Highlights

回复人：fengyu211,▲▲▲ (有东东共享) 时间：2005-10-09 12:36:15 编辑

3楼

Some literature about the Grubbs Reaction in Organic Synthesis:
J. Am. Chem. Soc. 2004, 126, 2495.
J. Am. Chem. Soc. 2000, 122. 8168
J. Am. Chem. Soc. 2004, 126, 2680
J. Am. Chem. Soc. 2003, 125, 10103
J. Am. Chem. Soc. 2003, 125, 11360
Org. Lett. 2004, 6, 493
Org. Lett. 2004, 6, 413
Org. Lett. 2004, 6, 525
Org. Lett. 2004, 6, 1883.
J. Org. Chem. 2004, 69, 4116
J. Org. Chem. 2004, 69, 4116
J. Org. Chem. 2004, 69, 3400
J. Org. Chem. 2003, 68, 6047.
J. Org. Chem. 2003, 68, 8867
J. Org. Chem., 2003, 68, 5672
Tetrahedron Lett. 2004, 45, 5309
Tetrahedron Lett. 2004, 45, 5211

回复人：fengyu211,▲▲▲ (有东东共享) 时间：2005-10-09 12:41:25 编辑

4楼

Cross Metathesis
The transalkylidenation of two terminal alkenes under release of ethene, catalyzed by ruthenium carbenoids (Grubbs Catalyst). Statistically, the reaction can lead to three possible pairs of geometric isomers, i.e. E/Z pairs for two homocouplings and the cross-coupling (R-CH=CH-R, R'-CH=CH-R', and R-CH=CH-R') - a total of 6 products.

The selectivity of this reaction is currently undergoing further study, but various examples exist in which two alkenes with different reactivity give the cross-coupled product with excellent yields and excellent selectivity.

Recent Literature
S. BouzBouz, R. Simmons, J. Cossy, Org. Lett., 2004, 6, 3465-3467.
K. Grela, M. Kim, Eur. J. Org. Chem., 2003, 963-966
T. W. Baughman, J. C. Sworen, K. B. Wagener, Tetrahedron, 2004, 60, 10943-10948

回复人：化学王子,★ (浩淼人生化学路，前途茫茫超自然！！) 时间：2005-10-09 13:45:43 编辑	5楼
对，今年诺贝尔化学奖的就是因为烯烃复分解反应！~希望大家能提供这方面的知识！~谢谢！~

回复人：sssyyysss,▲▲ () 时间：2005-10-17 09:59:50 编辑	6楼
接受答案了。

得分人：*元*素*-1,fengyu211-4,fengyu211-3,fengyu211-3,化学王子-1,

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