问题：美国化学会会志JACS发表的被引用最多的论文(转)
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1 10638 Lineweaver, H.; Burk, D. The Determination of Enzyme Dissociation Constants 1934, 56, 658–666

2 7623 Dewar, M. J. S.; Zoebisch, E. G.; Healy, E. F.; Stewart, J. J. P. AM1:
A New General Purpose Quantum Mechanical Molecular Model 1985, 107, 3902–3909

3 5373 Dewar, M. J. S.; Thiel, W. Ground States of Molecules. 38. The MNDO Method. Approximations and Parameters 1977, 99, 4899–4907

4 4808 Brunauer, S.; Emmett, P. H.; Teller, E. Adsorption of Gases in Multimolecular Layers 1938, 60, 309–319

5 4450 Merrifield, R. B. Solid Phase Peptide Synthesis. I. The Synthesis of a
Tetrapeptide 1963, 85, 2149–2154

6 2920 Onsager, L. Electric Moments of Molecules in Liquids 1936, 58, 1486–1493

7 2799 Binkley, J. S.; Pople, J. A.; Hehre, W. J. Self-Consistent Molecular Or
bital Methods. 21. Small Split-Valence Basis Sets for First-Row Elements 1980,
102, 939–947

8 2720 Allinger, N. L. Conformational Analysis. 130. MM2. A Hydrocarbon Force Field Utilizing V1 and V2 Torsional Terms 1977, 99, 8127–8134

9 2698 Sweeley, C. C.; Bentley, R.; Makita, M.; Wells, W. W. Gas–Liquid Chromatography of Trimethylsilyl Derivatives of Sugars and Related Substances 1963,
85, 2497–2507

10 2673 Weiner, S. J.; Kollman, P. A.; Case, D. A.; Singh, U. C.; Ghio, C.; Al
agona, G.; Profeta, S., Jr.; Weiner, P. A New Force Field for Molecular Mechanical Simulation of Nucleic Acids and Proteins 1984, 106, 765–784

11 2648 Benesi, H. A.; Hildebrand, J. H. A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons 1949, 71, 2703–2707

12 2645 Pedersen, C. J. Cyclic Polyethers and Their Complexes with Metal Salts 1967, 89, 7017–7036

13 2603 Pearson, R. G. Hard and Soft Acids and Bases 1963, 85, 3533–3539

14 2522 Williams, M. L.; Landel, R. F.; Ferry, J. D. The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids 1955, 77, 3701–3707

15 2384 Hammond, G. S. A Correlation of Reaction Rates 1955, 77, 334–338

16 2362 Cremer, D.; Pople, J. A. General Definition of Ring Puckering Coordinates 1975, 97, 1354–1358

17 2171 Karplus, M. Vicinal Proton Coupling in Nuclear Magnetic Resonance 1963, 85, 2870–2871

18 2074 Bingham, R. C.; Dewar, M. J. S.; Lo, D. H. Ground States of Molecules.
XXV. MINDO/3. Improved Version of the MINDO Semiempirical SCF-MO Method 1975, 97, 1285–1293

19 2045 Boyer, P. D. Spectrophotometric Study of the Reaction of Protein Sulfhydryl Groups with Organic Mercurials 1954, 76, 4331–4337

20 2022 Bax, A.; Summers, M. F. Proton and Carbon-13 Assignments from Sensitivity-Enhanced Detection of Heteronuclear Multiple-Bond Connectivity by 2D Multiple Quantum NMR 1986, 108, 2093–2094

21 1974 Mulliken, R. S. Molecular Compounds and their Spectra. II 1952, 74, 811–824

22 1961 Dewar, M. J. S.; Thiel, W. Ground States of Molecules. 39. MNDO Results for Molecules Containing Hydrogen, Carbon, Nitrogen, and Oxygen 1977, 99, 49
07–4917

23 1824 Corey, E. J.; Venkateswarlu, A. Protection of Hydroxyl Groups as tert-Butyldimethylsilyl Derivatives 1972, 94, 6190–6191

24 1636 Cohn, E. J.; Strong, L. E.; Hughes, W. L., Jr.; Mulford, D. J.; Ashworth, J. N.; Melin, M.; Taylor, H. L. Preparation and Properties of Serum and Plasma Proteins. IV. A System for the Separation into Fractions of the Protein and Lipoprotein Components of Biological Tissues and Fluids 1946, 68, 459–475

25 1631 Peterson, E. A.; Sober, H. A. Chromatography of Proteins. I. Cellulose Ion-Exchange Adsorbents 1956, 78, 751–755

Date Available: March 2003
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26 1588 Dale, J. A.; Mosher, H. S. Nuclear Magnetic Resonance Enantiomer Reagents. Configurational Correlations via Nuclear Magnetic Resonance Chemical Shifts of Diastereomeric d Mandelate, O-Methylmandelate, and -Methoxy--trifluoromethylphenylacetate (MTPA) Esters 1973, 95, 512–519

27 1469 Pople, J. A.; Gordon, M. Molecular Orbital Theory of the Electronic Structure of Organic Compounds. I. Substituent Effects and Dipole Moments 1967, 89, 4253–4261

28 1461 Hubbell, W. L.; McConnell, H. M. Molecular Motion in Spin-Labeled Phospholipids and Membranes 1971, 93, 314–326

29 1458 Borch, R. F.; Bernstein, M. D.; Durst, H. D. Cyanohydridoborate Anion as a Selective Reducing Agent 1971, 93, 2897–2904

30 1451 Altona, C.; Sundaralingam, M. Conformational Analysis of the Sugar Ring in Nucleosides and Nucleotides. New Des cription Using the Concept of Pseudorotation 1972, 94, 8205–8212

31 1431 Bothner-By, A. A.; Stephens, R. L.; Lee, J.; Warren, C. D.; Jeanloz, R. W. Structure Determination of a Tetrasaccharide: Transient Nuclear Overhauser Effects in the Rotating Frame 1984, 106, 811–813

32 1428 Wilson, G. M. Vapor–Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing 1964, 86, 127–130

33 1415 Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C.
T.; Schmitt, K. D.; Chu, C. T.-W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. A New Family of Mesoporous Molecular Si
eves Prepared with Liquid Crystal Templates 1992, 114, 10834–10843

34 1369 Brown, H. C.; Okamoto, Y. Electrophilic Substituent Constants 1958, 80, 4979–4987

35 1367 Anderson, G. W.; Zimmerman, J. E.; Callahan, F. M. The Use of Esters of N-Hydroxysuccinimide in Peptide Synthesis 1964, 86, 1839–1842

36 1348 Sheehan, J. C.; Hess, G. P. A New Method of Forming Peptide Bonds 1955, 77, 1067–1068

37 1310 Hinze, J.; Jaffé, H. H. Electronegativity. I. Orbital Electronegativi
ty of Neutral Atoms 1962, 84, 540–546

38 1304 Wani, M. C.; Taylor, H. L.; Wall, M. E.; Coggon, P.; McPhail, A. T. Pl
ant Antitumor Agents. VI. Isolation and Structure of Taxol, a Novel Antileukemic and Antitumor Agent from Taxus brevifolia 1971, 93, 2325–2327

39 1299 Fujita, T.; Iwasa, J.; Hansch, C. A New Substituent Constant, , Derived from Partition Coefficients 1964, 86, 5175–5180

40 1294 Stork, G.; Brizzolara, A.; Landesman, H.; Szmuszkovicz, J.; Terrell, R
. The Enamine Alkylation and Acylation of Carbonyl Compounds 1963, 85, 207–222

41 1294 Teo, B.-K.; Lee, P. A. Ab Initio Calculations of Amplitude and Phase Functions for Extended X-ray Absorption Fine Structure Spectroscopy 1979, 101, 2815–2832

42 1276 Langmuir, I. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum 1918, 40, 1361–1403

43 1274 Porter, M. D.; Bright, T. B.; Allara, D. L.; Chidsey, C. E. D. Spontan
eously Organized Molecular Assemblies. 4. Structural Characterization of n-Alk
yl Thiol Monolayers on Gold by Optical Ellipsometry, Infrared Spectroscopy, an
d Electrochemistry 1987, 109, 3559–3568

44 1261 Hansch, C.; Fujita, T. -- Analysis. A Method for the Correlation of Bi
ological Activity and Chemical Structure 1964, 86, 1616–1626

45 1253 Kay, E. R. M.; Simmons, N. S.; Dounce, A. L. An Improved Preparation of Sodium Desoxyribonucleate 1952, 74, 1724–1726

Date Available: May 2003
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46 1251 Fuoss, R. M. Ionic Association. III. The Equilibrium between Ion Pairs
and Free Ions 1958, 80, 5059–5061

47 1249 Kosower, E. M. The Effect of Solvent on Spectra. I. A New Empirical Measure of Solvent Polarity: Z-Values 1958, 80, 3253–3260

48 1223 Ammeter, J. H.; Buergi, H.-B.; Thibeault, J. C.; Hoffman, R. Counterintuitive Orbital Mixing in Semiempirical and ab Initio Molecular Orbital Calculations 1978, 100, 3686–3692

49 1222 Piantini, U.; Sorensen, O. W.; Ernst, R. R. Multiple Quantum Filters f
or Elucidating NMR Coupling Networks 1982, 104, 6800–6801

50 1216 Bain, C. D.; Troughton, E. B.; Tao, Y.-T.; Evall, J.; Whitesides, G. M
.; Nuzzo, R. G. Formation of Monolayer Films by the Spontaneous Assembly of Organic Thiols from Solution onto Gold 1989, 111, 321–335

回复人：fengyu211,▲▲▲ (有东东共享) 时间：2005-10-28 13:05:36 编辑	1楼
资源不错，加0.1分

回复人：laihama,▲▲▲ (从水热合成纳米材料转行搞有机合成，正在上路中。。。) 时间：2005-11-02 12:02:36 编辑	2楼
没想到第一的竟然是1934年的

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