问题：求助氟化氨热分解温度。
类型：求助 (悬赏分:3分)
提问：xuefeng
等级：▲
版块：无机化学(mitang,lmybenny,wanghong,llscmary,abingchem,)
信誉：100%
回复：3
阅读：727
时间：2005-11-08 08:58:33 编辑加入/取消收藏订制/取消短消息举报该贴

求助氟化氨热分解温度

回复人：wangjinyon,★ (化工成就了我,我会成就化工) 时间：2005-11-08 14:09:57 编辑	1楼
100度

回复人：wangjinyon,★ (化工成就了我,我会成就化工) 时间：2005-11-08 14:11:12 编辑

2楼

这是其安全数据表
分解温度在第9项
为100度

Language: EN
Country:

**** MATERIAL SAFETY DATA SHEET ****

Ammonium Fluoride
01230

**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****

MSDS Name: Ammonium Fluoride
Catalog Numbers:
A/4920, A/4960
Synonyms:
Neutral ammonium fluoride
Company Identification: Fisher Scientific UK
Bishop Meadow Road
Loughborough, Leicestershire
LE11 5RG, UK
For information, call: 01509 231166
For emergencies, call: 01509 231166

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
| 12125-01-8 |AMMONIUM FLUORIDE | 100 | 235-185-9 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Hazard Symbols: T
Risk Phrases: 23/24/25

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.

Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause deep, penetrating ulcers of the skin. May cause severe
irritation and possible burns.
Ingestion:
May cause vascular collapse and damage. Causes severe digestive
tract burns with abdominal pain, vomiting, and possible death. May
cause hemorrhaging of the digestive tract.
Inhalation:
Causes delayed lung injury. May cause severe respiratory tract
irritation.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
Wear appropriate protective clothing to prevent contact with skin
and eyes. Wear a self-contained breathing apparatus (SCBA) to
prevent contact with thermal decomposition products.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not get on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a tightly closed container. Keep from contact with
oxidizing materials. Store in a cool, dry, well-ventilated area away
from incompatible substances. Keep away from water. Keep away from
acids. Keep away from strong bases.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Local exhaust ventilation may be necessary to control any air
contaminants to within their TLVs during the use of this product.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: White, granular, deliquescent powder or crystals.
Odor: Odorless.
pH: Acidic
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Decomposes.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 100 C
Solubility in water: Completely soluble in water.
Specific Gravity/Density: 1.009
Molecular Formula: NH4F
Molecular Weight: 37.0331

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, moisture, contact with water, acids, excess
heat, strong oxidants, bases.
Incompatibilities with Other Materials:
Reacts with acids to produce hydrogen fluoride; reacts with bases to
products ammonia. Contacts with water may lead to corrosion of metal
and possibly the formation of highly explosive hydrogen gas. Corrodes
glass. Incompatible with quinine salts, and soluble calcium salts.
Hazardous Decomposition Products:
Oxides of nitrogen, hydrogen fluoride gas, ammonia and/or
derivatives.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 12125-01-8: BQ6300000
LD50/LC50:
Not available.
Carcinogenicity:
AMMONIUM FLUORIDE -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: AMMONIUM FLUORIDE
Hazard Class: 6.1
UN Number: 2505
Packing Group: III
IMO
Shipping Name: AMMONIUM FLUORIDE
Hazard Class: 6.1
UN Number: 2505
Packing Group: III
RID/ADR
Shipping Name: AMMONIUM FLUORIDE
Hazard Class: 6.1
UN Number: 2505
Packing group: III
USA RQ:CAS# 12125-01-8: 100 lb final RQ; 45.4 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 1/2 Keep locked up and out of reach of children.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 12125-01-8: 1
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
CAS# 12125-01-8 is listed on Canada's DSL List.
CAS# 12125-01-8 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 12125-01-8: OEL-AUSTRALIA:TWA 2.5 mg(F)/m3
OEL-BELGIUM:TWA 2.5 mg(F)/m3
OEL-CZECHOSLOVAKIA:TWA 1 mg(F)/m3;STEL 5 mg(F)/m3
OEL-DENMARK:TWA 2.5 mg(F)/m3
OEL-FINLAND:TWA 2.5 mg(F)/m3
OEL-FRANCE:TWA 2.5 mg(F)/m3
OEL-GERMANY:TWA 2.5 mg(F)/m3
OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3
OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3
OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3
OEL-POLAND:TWA 1 mg(F)/m3
OEL-RUSSIA:TWA 0.2 mg/m3;STEL 1 mg/m3
OEL-SWEDEN:TWA 2 mg(F)/m3
OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm
OEL-THAILAND:TWA 2.5 mg(F)/m3
OEL-TURKEY:TWA 2.5 mg(F)/m3
OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 12125-01-8 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 3/09/1995 Revision #0 Date: Original.

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------

回复人：xuefeng,▲ (不留任何遗憾，不错过任何机遇。) 时间：2005-11-08 18:57:51 编辑	3楼
已经打分了。

得分人：wangjinyon-3,

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